DEVELOPMENT AND EVALUATION OF ENVELOPE, SPECTRAL AND TIME ENHANCEMENT ALGORITHMS FOR AUDITORY NEUROPATHY

Auditory neuropathy (AN) is a hearing disorder that reduces the ability to detect temporal cues in speech, thus leading to deprived speech perception. Traditional amplification and frequency shifting techniques used in modern hearing aids are not suitable to assist individuals with AN due to the unique symptoms that result from the disorder. This study proposes a method for combining both speech envelope enhancement and time scaling to combine the proven benefits of each algorithm. In addition, spectral enhancement is cascaded with envelope and time enhancement to address the poor frequency discrimination in AN. The proposed speech enhancement strategy was evaluated using an AN simulator with normal hearing listeners under varying degrees of AN severity. The results showed a significant increase in word recognition scores for time scaling and envelope enhancement over envelope enhancement alone. Furthermore, the addition of spectral enhancement resulted in further increase in word recognition at profound AN severity

Projective Normality and Ehrhart Unimodality for Weighted Projective Space Simplices

Within the intersection of Ehrhart theory, commutative algebra, and algebraic geometry lie lattice polytopes. Ehrhart theory is concerned with lattice point enumeration in dilates of polytopes; lattice polytopes provide a sandbox in which to test many conjectures in commutative algebra; and many properties of projectively normal toric varieties in algebraic geometry are encoded through corresponding lattice polytopes. In this article we focus on reflexive simplices and work to identify when these have the integer decomposition property (IDP), or equivalently, when certain weighted projective spaces are projectively normal. We characterize the reflexive, IDP simplices whose associated weighted projective spaces have one projective coordinate with weight fixed to unity and for which the remaining coordinates can assume one of three distinct weights. We show that several subfamilies of such reflexive simplices have unimodal $h^\ast$-polynomials, thereby making progress towards conjectures and questions of Stanley, Hibi-Ohsugi, and others regarding the unimodality of their $h^\ast$-polynomials. We also provide computational results and introduce the notion of reflexive stabilizations to explore the (non-)ubiquity of reflexive simplices that are simultaneously IDP and $h^\ast$-unimodal

Reflections on an Introduction to Project Based Engineering in an Incarcerated Setting

Education programs in incarcerated settings have a goal of improving the current and future lives of the currently incarcerated individuals. There are many programs that support earning a GED, associate degree, or baccalaureate degree when incarcerated. The benefits of these programs include improved behavior while incarcerated, reduced recidivism, and broadening the workforce. Generally, the courses offered as a part of these programs are general education in nature. This paper discusses an Introduction to Project Based Engineering taught in a women’s prison setting. Specifically, it explores the course as a case study reflected on from several angles. Each reflection illuminates the case from a different perspective. The different perspectives are a prison administrator, the instructor, the author of one of the textbooks used in the course, a student more than a decade from release, and a student a few months from release. By taking these reflections together one is able to see the challenges, rewards, and opportunities associated with teaching an Introduction to Project Based Engineering to incarcerated women. Although each perspective highlights different aspects of the course there are common themes. There are also key differences that illustrate the unique needs and wants of the various stakeholders. The common themes and differences are examined. Together they serve as a foundation for adjusting the course to make it more effective and sustainable. Additionally, the reflections examined here shed light on how an Introduction to Project Based Engineering in a traditional setting might be improved

Small variations in reaction conditions tune carbon dot fluorescence

The development of robust and reproducible synthetic strategies for the production of carbon dots with improved fluorescence quantum yields and distinct emission profiles is of great relevance given the vast range of applications of CDs. The fundamental understanding at a molecular level of their formation mechanism, chemical structure and how these parameters are correlated to their photoluminescence (PL) properties is thus essential. In this study, we describe the synthesis and structural characterization of a range of CDs with distinct physico-chemical properties. The materials were prepared under three minutes of microwave irradiation using the same common starting materials (GlcNH2·HCl 1 and EDA 2) but modifying the stoichiometry of the reagents. We show that small changes in reaction conditions leads to the tailoring of the fluorescent behaviour of the CDs from apparent blue to green emission. Structural analysis of the different CD samples suggested different reaction pathways during the CD formation and surface passivation, with the latter step being key to the observed differences. Moreover, we demonstrate that the different materials also respond reversibly to changes in pH, which we can attribute to different behaviour towards protonation/deprotonation events of distinct emission domains present within each nanomaterial. Our results highlight the importance of understanding the reaction pathways that lead to the formation of this carbon-based nanomaterials and how this can be exploited to develop tailored materials towards specific applications

Heterogenized Iridium Water-Oxidation Catalyst from a Silatrane Precursor

A pentamethylcyclopentadienyl (Cp*) iridium water-oxidation precatalyst was modified to include a silatrane functional group for covalent attachment to metal oxide semiconductor surfaces. The heterogenized catalyst was found to perform electrochemically driven water oxidation at an overpotential of 462 mV with a turnover number of 304 and turnover frequency of 0.035 s^(–1) in a 0.1 M KNO3 electrolyte at pH 5.8. Computational modeling of the experimental IR spectra suggests that the catalyst retains its Cp* group during the first hour of catalysis and likely remains monomeric